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Corrosion Rates in the Dew-Point Zone of Superheated Steam

Giorgio Culivicchi, Renato Perini, Bruno Tarquini and Alessandro Lenzi

Key words
geothermal, geochemical, carbon steel, stainless steel, chloride corrosion, Larderello
Conference
World Geothermal Congress
Year
2000
Session
Power Generation
Language
English
Paper number
R0739

Full text

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Abstract

The corrosion rates of carbon steel and 13% Cr stainless steel when superheated steam begins to condense on the metal surface were experimentally measured. Generalised and pitting corrosion in the geothermal fluid was monitored by weight-loss in steam-inserted cooled coupons. In these conditions, the surface is wetted by an acid film due to the hydrogen and ammonia chloride dissolution. Tests were made in several steams with chloride concentration ranging between 0 and 10 ppm. The correlation y=0.315. [Cl]steam has been determined as the relationship between the corrosion rate and chloride content.

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