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Sulfur and Base Metal Transport in the Salton Sea Geothermal System

McKibben, Michael A.; Eldridge, C. Stewart; Williams, Alan E.

Key words
Exploration; USA; California; Imperial; Salton Sea; Chemical Analysis; Chemistry; Chloride; Geochemistry; Mineralization; Salinity; Sulfur; Water Rock Reaction; Ore Minerals; Geology; Temperature; High Temperature; Hydrothermal; H2S; Sulfate; Isotopes
Location
Salton Sea, California; Imperial Valley
Conference
Geothermal Resources Council Transactions
Year
1988
Session
Exploration; Geochemical surveys; Isotopes; Sulfur
Language
English

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Abstract

Sulfur isotope data demonstrate that H2S in the SSGS brines is generated by partial hydrothermal reduction of SO4/2- derived from dissolution of lacrustrine sulfate minerals in the host sediments. No magmatic input of sulfur is indicated. SO4/2- reduction is promoted by interaction of the sediments with an upwelling diapir of Fe2+ rich hypersaline brine. Base metals are carried in the brines as the chloride complexes PbCl3-, ZnCl2/0, CdCl2/0, CuCl3/2- and MnCl2/0. Fe is probably carried as both FeCl3- and FeCl4- complexes. Vein sulfide precipitation within the reservoir occurs during brine dilution and oxidation at an interface between the hypersaline brines and overlying more oxidized lower salinity fluids.

Copyright 1988, Geothermal Resources Council. Readers who download papers from this site should honour the copyright of the original authors, and may not copy or distribute the work further without the permission of the original publisher.

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